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Skaarup Christiansen posted an update 4 days, 9 hours ago
14 ± 0.03 kW h/m3), but higher for the O3/UV process (0.21-0.22 kW h/m3). These results suggest that single ozonation is unable to sufficiently abate thiamethoxam under typical conditions of water treatment. Therefore, ozone-based advanced oxidation processes are needed to enhance thiamethoxam abatement. The fundamental mechanism behind oil/water separation materials is their surface wettability that allows either oil or water to pass through. The conventional materials for oil/water separation generally have extreme wettability, namely superhydrophilic for water separation and superhydrophobic for oil separation. Using easily accessible materials that are medium hydrophobic or even relatively hydrophilic for preparing highly efficient oil/water separators have rarely been reported. In this work, a new strategy by triggering phase transition of infused lubricant from liquid to solid state in porous structure is realized in fabricating slippery lubricant infused porous structure for oil/water separations. By infusing polyester fabric with coconut oil, after phase transition, excellent water repellency and oil permeability by an absorbing-permeating mechanism are achieved, despite the low water contact angle on the new material. Although the new phase transformable slippery lubricant infused porous structure, features much milder hydrophobicity than conventional oil/water separators, it can remove diverse types of oil from water with high efficiencies. The phase transformable slippery lubricant infused porous structure is able to maintain their water repellency after immersing in high concentration salt (10 wt% NaCl), acid (25 % HCl), alkaline (25 % NH3·H2O) solutions for 120 h, showing remarkably functional durability in harsh environment. The lubricant phase transition mechanism proposed in this study is universally applicable to porous substrates with various chemical compositions and pore structures, such as porous sponges or even daily life breads, for creating efficient oil/water separators, which can serve as a novel accessible design principle of phase transformable slippery lubricant infused porous structure for eco-friendly oil/water separators. Fe-Mn nodules are widely distributed and regarded as excellent adsorbents for heavy metals. Their adsorption-desorption reactions with heavy metal ions are usually accompanied by redox processes. Herein, Fe-Mn nodules were used as adsorbents for Cd(II) and As(III,V) at a constant cell voltage under electrochemically controlled reduction and oxidation, respectively. The results showed that the adsorption performance for Cd(II) and As(III,V) was enhanced respectively due to the decrease and increase of Mn average oxidation state (Mn AOS) in Fe-Mn nodules. High birnessite content and Mn average oxidation state (Mn AOS) improved the adsorption of Cd(II) and As(III,V). The adsorption capacity for Cd(II) and total As increased with increasing voltage. With increasing pH, the adsorption capacity for Cd(II) increased first and then reached equilibrium, and that of total As decreased and then increased. The Cd(II) electrochemical adsorption capacity (129.9 mg g-1) and the removal efficiency for total As at 1.2 V (83.6 %) in As-containing wastewater at an initial concentration of 4.068 mg L-1 were remarkably higher than the corresponding inorganic adsorption performance (9.46 mg g-1 and 70.5 %, respectively). This work may further promote the application of natural Fe-Mn nodules in the adsorption of heavy metals from wastewaters. Adsorption technology has been widely applied in water and wastewater treatment, due to its low cost and high efficiency. The adsorption kinetic models have been used to evaluate the performance of the adsorbent and to investigate the adsorption mass transfer mechanisms. However, the physical meanings and the solving methods of the kinetic models have not been well established. TP-0184 The proper interpretation of the physical meanings and the standard solving methods for the adsorption kinetic models are very important for the applications of the kinetic models. This paper mainly focused on the physical meanings, applications, as well as the solving methods of 16 adsorption kinetic models. Firstly, the mathematical derivations, physical meanings and applications of the adsorption reaction models, the empirical models, the diffusion models, and the models for adsorption onto active sites were analyzed and discussed in detail. Secondly, the model validity evaluation equations were summarized based on literature. Thirdly, a convenient user interface (UI) for solving the kinetic models was developed based on Excel software and provided in supplementary information, which is helpful for readers to simulate the adsorption kinetic process. The major focus of the recent studies in metals corrosion protection field is now the development of non-hazardous and eco-friendly materials as effective substitutes for some of the well-known conventional toxic/unsafe inhibitors based on chromate, lead, phosphate, and azole derivatives. The present work focuses on the sustainable development of an intelligent self-healing anticorrosion coating using nanocarriers based on the graphene oxide nanoplatform-Tamarindus indiaca extract-Zn2+ (GON-Ti.E-Zn)-through a facile green assisted route. The GON-Ti.E-Zn nanocarrier was introduced into the epoxy ester film (EEF) to achieve a smart barrier/self-healing anti-corrosive property. To this end, a couple of characterization tests, including FT-IR, UV-vis, XRD, TGA, and Raman spectroscopy, have been carried out to investigate the GON-Ti.E-Zn nanocarrier structure/composition. The effectiveness of the anti-corrosion performance of the established coatings was confirmed by EIS, FE-SEM, and accelerated salt spray (SS) test. The observation of the high impedance magnitude at low-frequency (47.14 Gohm cm2 after 5 weeks immersion in saline solution) for the un-defected EEF and significant impedance enhancement for the defected EEF including GON-Ti.E-Zn nanocarrier confirmed the excellent barrier effect of GO and synergistic behavior and noticeable corrosion inhibition impact of Tamarindus indiaca along with the zinc cations on the mild steel corrosion mitigation.